Ultraviolet Lasers
Definition: lasers (or other laser-based light sources) generating ultraviolet light
More general terms: lasers
German: ultraviolette Laser
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Author: Dr. RĂ¼diger Paschotta
The technology of lasers for the generation of ultraviolet light involves a number of challenges:
- For short wavelengths, strong spontaneous emission leads to a high threshold pump power (except when the gain bandwidth is narrow).
- For wavelengths below ≈ 200 nm, the choice of transparent and UV-resistant optical materials is fairly limited (see the article on ultraviolet light).
- Even weak surface roughness or bubble content of optical components can lead to strong wavefront distortions and scattering losses.
Nevertheless, there are various kinds of lasers which can directly generate ultraviolet light:
- There are laser diodes, normally based on gallium nitride (GaN), emitting in the near-ultraviolet region. The available power levels, however, are limited.
- Some solid-state bulk lasers, e.g. based on cerium-doped crystals such as Ce3+:LiCAF or Ce3+:LiLuF4, can emit ultraviolet light. Cerium lasers are in most cases pumped with nanosecond pulses from a frequency-quadrupled Q-switched laser, and thus emit nanosecond pulses themselves. With Q-switched microchip lasers, even sub-nanosecond pulse durations are possible. Mode-locked operation has also been demonstrated [13].
- Few fiber lasers can generate ultraviolet light [9]. For example, some neodymium-doped fluoride fibers can be used for lasers emitting around 380 nm, but only at low power levels.
- Although most dye lasers emit visible light, some laser dyes are suitable for ultraviolet emission.
- Excimer lasers are very powerful UV sources, also emitting nanosecond pulses, but with average output powers between a few watts and hundreds of watts. Typical wavelengths are between 157 nm (F2) and 351 nm (XeF).
- Argon ion lasers can continuously emit at wavelengths of 334 and 351 nm, even though with lower powers than on the usual 514-nm line. Some other ultraviolet lines are accessible with krypton ion lasers.
- There are also ion lasers emitting in the extreme ultraviolet spectral region. These can be based on, e.g., argon, but unlike in ordinary argon ion lasers one operates with Ar8+ ions, generated in a much hotter plasma. The emission then occurs at 46.9 nm. Such lasers can be pumped either with a capillary discharge or with an intense laser pulse.
- Nitrogen lasers are molecular gas lasers emitting in the ultraviolet. The strongest emission line is at 337.1 nm.
- Free electron lasers can emit ultraviolet light of essentially any wavelength, and with high average powers. However, they are very expensive and bulky sources, and are therefore not very widely used.
Apart from real ultraviolet lasers, there are ultraviolet laser sources based on a laser with a longer wavelength (in the visible or near-infrared spectral region) and one or several nonlinear crystals for nonlinear frequency conversion. Some examples:
- The wavelength of 355 nm can be generated by frequency tripling the output of a 1064-nm Nd:YAG or Nd:YVO4 laser.
- 266-nm light is obtained with two subsequent frequency doublers, which in effect quadruple the laser frequency.
- Diode lasers can be equipped with nonlinear frequency conversion stages to produce UV light. For example, one may use a continuous-wave near-infrared laser and apply resonant frequency doubling twice, arriving at wavelengths around 300 nm. A main attraction of this approach is that a wide range of wavelengths is accessible, with no limitations to certain laser lines.
Ultraviolet lasers need to be made with special ultraviolet optics, having a high optical quality and (particularly for pulsed lasers) a high resistance to UV light. In some cases, the lifetime of a UV laser is limited by the lifetime of the used optical elements such as laser mirrors.
For the extreme ultraviolet region, there are sources based on high harmonic generation. Such sources can reach wavelengths down to a few nanometers while still having a table-top format. The average output powers, however, are fairly low.
Applications
Ultraviolet lasers find various applications:
- Pulsed high-power ultraviolet lasers can be used for efficient cutting and drilling of small holes in a variety of materials, including materials which are transparent to visible light.
- Continuous-wave UV sources are required for micro-lithography, e.g. in the context of semiconductor chip manufacturing.
- Both continuous-wave and pulsed UV lasers are used for fabricating fiber Bragg gratings.
- Some methods of eye surgery, in particular refractive laser eye surgery of the cornea in the form of LASIK, require UV (sometimes even deep-UV) laser sources.
Ultraviolet laser sources involve some special safety hazards, mostly related to the risks of eye damage and causing skin cancer. The article on laser safety gives some details.
Suppliers
The RP Photonics Buyer's Guide contains 81 suppliers for ultraviolet lasers. Among them:
NKT Photonics
As part of our PILAS range of gain-switched pulsed diode lasers, we offer an ultraviolet laser: The PiL037 with a wavelength of 375 nm. All PILAS lasers offer triggable pulses down to 20 ps in a small footprint for both scientific and OEM applications. Available with output wavelengths from 375 nm to 1.6 μm, the PILAS lasers are very versatile and comes with low timing jitter, maintenance-free operation, and low cost of ownership.
Frankfurt Laser Company
Frankfurt Laser Company offers UV and violet laser diodes from with emission wavelengths from 370 nm to 420 nm.
LightMachinery
LightMachinery excimer lasers are powerful and reliable sources for ultraviolet light. They now feature exciPure™ technology, introduced in 2016; exciPure represents the greatest improvement in excimer gas lifetime and reduction in operating costs in a generation.
The IPEX-700 Seris is designed for medium duty cycle operation in industrial and R & D environments. These lasers deliver high power ultraviolet laser machining combined with state-of-the-art performance. They are ideal for applications such as pulsed laser deposition.
The IPEX-800 series is designed for high duty cycle operation in a manufacturing environment. These lasers deliver high power ultraviolet laser machining combined with state-of-the-art performance. They offer long gas lifetimes, superior optical stability and precise control of laser operating parameters. Easy to use, simple to service and economical to operate, they combine the benefits of high precision excimer processing with the lowest total cost of ownership and highest uptime in the market today.
RPMC Lasers
RPMC Lasers offers a wide range of ultraviolet diode and DPSS lasers between 200 nm and 389 nm. These offerings includer pulsed and CW lasers and modules with packaging at all levels of integration from TO can through turnkey system.
TOPTICA Photonics
TOPTICA provides lasers in the UV range from 190 nm – 390 nm. Proprietary technology and high-end clean room manufacturing capabilities enable stable long-term operation at all wavelengths.
Teem Photonics
Sub-nanosecond passively Q-switched microchip lasers are available with emission wavelengths of 355 nm and 266 nm.
For higher peak powers, we offer the 266 nm PNU-M01210-1x0 lasers, part of the Powerchip series, also available with various wavelengths including 355 nm, 266 nm and 213 nm. Peak powers of tens of kilowatts (or even 160 kW at 1064 nm) are generated, while the pulse durations are always well below a nanosecond. These lasers use a specific long life process to extend lifetime between refurbishments.
Kapteyn-Murnane Laboratories
KMLabs Hyperion VUV provides bright femtosecond pulses at numerous wavelengths across the vacuum ultraviolet (VUV) region, from 6.0 eV (205 nm) to 10.8 eV (115 nm). The discrete tunability of the KMLabs Hyperion VUV vacuum ultraviolet source enables researchers to study a wide range of materials and materials properties. A simple computer-selected change of photon energy provides a powerful capability, previously only available at a synchrotron; this ability to easily change the laser wavelength can enhance many experiments. For example, in angle-resolved photoemission (ARPES) experiments, this tunability allows researchers to distinguish surface effects from bulk effects. For time-of-flight (ToF) studies of molecules, the tunability can distinguish otherwise identical isomers. Hyperion VUV is also highly focusable, and the appropriate optics can be used to reach spot sizes below 10 microns.
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Bibliography
[1] | H. Furumoto and H. Ceccon, “Ultraviolet organic liquid lasers”, IEEE J. Quantum Electron. 6 (5), 262 (1970), doi:10.1109/JQE.1970.1076451 |
[2] | C. Rhodes, “Review of ultraviolet lasers”, IEEE J. Quantum Electron. 9 (6), 647 (1973), doi:10.1109/JQE.1973.1077652 |
[3] | D. J. Ehrlich et al., “Optically pumped Ce:LaF3 laser at 286 nm”, Opt. Lett. 5 (8), 339 (1980), doi:10.1364/OL.5.000339 |
[4] | R. W. Waynant and P. H. Klein, “Vacuum ultraviolet laser emission from Nd3+:LaF3”, Appl. Phys. Lett. 46, 14 (1985), doi:10.1063/1.95833 |
[5] | Y. Taira, “High-power continuous-wave ultraviolet generation by frequency doubling of an argon laser”, Jpn. J. Appl. Phys. 31, L682 (1992), doi:10.1143/JJAP.31.L682 |
[6] | S. C. Tidwell et al., “Efficient high-power UV generation by use of a resonant ring driven by a CW mode-locked IR laser”, Opt. Lett. 18 (18), 1517 (1993), doi:10.1364/OL.18.001517 |
[7] | J. F. Pinto et al., “Tunable solid-state laser action in Ce3+:LiSrAlF6”, Electron. Lett. 30, 240 (1994), doi:10.1049/el:19940158 |
[8] | S. M. Hooker and C. E. Webb, “Progress in vacuum ultraviolet lasers”, Prog. Quantum Electron. 18 (3), 227 (1994), doi:10.1016/0079-6727(94)90002-7 |
[9] | D. S. Funk and J. G. Eden, “Glass-fiber lasers in the ultraviolet and visible”, J. Sel. Top. Quantum Electron. 1 (3), 784 (1995), doi:10.1109/2944.473660 |
[10] | T. Kojima et al., “20-W ultraviolet-beam generation by fourth-harmonic generation of an all-solid-state laser”, Opt. Lett. 25 (1), 58 (2000), doi:10.1364/OL.25.000058 |
[11] | C. Gohle et al., “A frequency comb in the extreme ultraviolet”, Nature 436, 234 (2005), doi:10.1038/nature03851 |
[12] | H. Liu et al., “Broadly tunable ultraviolet miniature cerium-doped LiLuF lasers”, Opt. Express 16 (3), 2226 (2008), doi:10.1364/OE.16.002226 |
[13] | E. Granados et al., “Mode-locked deep ultraviolet Ce:LiCAF laser”, Opt. Lett. 34 (11), 1660 (2009), doi:10.1364/OL.34.001660 |
[14] | J. Rothhardt et al., “100 W average power femtosecond laser at 343 nm”, Opt. Lett. 41 (8), 1885 (2016), doi:10.1364/OL.41.001885 |
[15] | U. Eismann et al., “Active and passive stabilization of a high-power UV frequency-doubled diode laser”, arXiv:1606.07670v1 (2016) |
See also: ultraviolet light, lasers, excimer lasers, free electron lasers, blue lasers, laser safety
and other articles in the category lasers
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